Effect of Salt Concentration, Solvent Donor Number and Coordination Structure on the Variation of the Li/Li+ Potential in Aprotic Electrolytes

The use of concentrated aprotic electrolytes in lithium batteries provides numerous potential applications, including the use of high-voltage cathodes and Li-metal anodes. In this paper, we aim at understanding the effect of salt concentration on the variation of the Li/Li+ Quasi-Reference Electrode (QRE) potential in Tetraglyme (TG)-based electrolytes. Comparing the obtained results to those achieved using Dimethyl sulfoxide DMSO-based electrolytes, we are now able to take a step forward and understand how the effect of solvent coordination and its donor number (DN) is attributed to the Li-QRE potential shift. Using a revised Nernst equation, the alteration of the Li redox potential with salt concentration was determined accurately. It is found that, in TG, the Li-QRE shift follows a different trend than in DMSO owing to the lower DN and expected shorter lifespan of the solvated cation complex.