Contributors: Ali I. Al-Naimi Petroleum Engineering Research Center (ANPERC), Physical Science & Engineering Division, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia; Physical Science and Engineering (PSE) Division; Energy Resources and Petroleum Engineering Program; Ali I. Al-Naimi Petroleum Engineering Research Center (ANPERC); School of Engineering, Edith Cowan University, Joondalup, WA 6027, Australia; Mechanical Engineering Department, College of Engineering and Islamic Architecture, Umm Al-Qura University, P.O. 5555, Makkah 24382, Saudi Arabia; Department of Petroleum Engineering, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Perak, Malaysia
Abstract: Hydrogen (H2) is a clean fuel and key enabler of energy transition into green renewable sources and a method of achieving net-zero emissions by 2050. Underground H2storage (UHS) is a prominent method offering a permanent solution for a low-carbon economy to meet the global energy demand. However, UHS is a complex procedure where containment security, pore-scale scattering, and large-scale storage capacity can be influenced by H2contamination due to mixing with cushion gases and reservoir fluids. The literature lacks comprehensive investigations of existing thermodynamic models in calculating the accurate transport properties of H2-blend mixtures essential to the efficient design of various H2storage processes. This work benchmarks cubic equations of state (EoSs), namely Peng–Robinson (PR) and Soave Redlich–Kwong (SRK) and their modifications by Boston–Mathias (PR-BM) and Schwartzentruber–Renon (SR-RK), for their reliability in predicting the thermophysical properties of binary and ternary H2-blend mixtures, including CH4, C2H6, C3H8, H2S, H2O, CO2, CO, and N2, in addition to Helmholtz-energy-based EoSs (i.e., PC-SAFT and GERG2008). The benchmarked models are regressed against the experimental data for vapor–liquid equilibrium (VLE) that covers a wide range of pressures (0.01 to 101 MPa), temperatures (92 K to 367 K), and mole fractions (0.001 to 0.90) of H2. The novelty of this work is in benchmarking and optimizing the parameters of the mentioned EoSs to study VLE envelopes, densities, and other critical transport properties, such as heat capacity and the Joule–Thomson coefficient of H2mixtures in a wide range of associated conditions. The results highlight the significant effect of the temperature-dependent binary interaction parameters on the calculations of thermophysical properties. The SR-RK EoS demonstrated the highest agreement with VLE data among the cubic EoSs with a low root mean square error and absolute average deviation. The PC-SAFT VLE models demonstrated results comparable to the SR-RK. The sensitivity analysis highlighted the high influence of impurity on changing the thermophysical behavior of H2-blend streams during the H2storage process.
Processing Request
No Comments.