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Trace Metal Thermodynamic Speciation With Humic Substances: The Nica-Donnan Model ; Especiação Termodinâmica De Metais Traço Com Substâncias Húmicas: O Modelo Nica-Donnan

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  • Additional Information
    • Contributors:
      Laboratoire Interdisciplinaire des Environnements Continentaux (LIEC); Institut Ecologie et Environnement - CNRS Ecologie et Environnement (INEE-CNRS); Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Terre et Environnement de Lorraine (OTELo); Institut national des sciences de l'Univers (INSU - CNRS)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS); Universidade Estadual Paulista Júlio de Mesquita Filho = São Paulo State University (UNESP)
    • Publication Information:
      HAL CCSD
      Sociedade Brasileira de Química
    • Publication Date:
      2017
    • Collection:
      Institut national des sciences de l'Univers: HAL-INSU
    • Abstract:
      International audience ; Trace Metal Thermodynamic Speciation With Humic Substances: The Nica-Donnan Model. This work presents a critical overview of the NICA-Donnan model for trace metal thermodynamic speciation with humic substances obtained from natural organic matter in soils, natural waters and anthropogenic sources. A first part covers the theoretical aspects of the model, how to obtain good experimental data and perform the modelling. A second part deals with the developments in the last decade namely the use of the generic parameters, criticism and alternatives to the electrostatic modeling, the understanding of the NICA equation and an analysis of the published data, ending with the needs and opportunities for model development.
    • Accession Number:
      10.21577/0100-4042.20170107
    • Online Access:
      https://hal.univ-lorraine.fr/hal-03150297
      https://hal.univ-lorraine.fr/hal-03150297v1/document
      https://hal.univ-lorraine.fr/hal-03150297v1/file/n84_QuimicaNova_NICADonnan_RV20170040.pdf
      https://doi.org/10.21577/0100-4042.20170107
    • Rights:
      info:eu-repo/semantics/OpenAccess
    • Accession Number:
      edsbas.1B6D1FC0