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Numerical Modelling for the Experimental Improvement of Growth Uniformity in a Halide Vapor Phase Epitaxy Reactor for Manufacturing beta-Ga2O3 Layers

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  • Additional Information
    • Publication Information:
      Linköpings universitet, Tunnfilmsfysik
      Linköpings universitet, Tekniska fakulteten
      Linköpings universitet, Halvledarmaterial
      MDPI
    • Publication Date:
      2022
    • Collection:
      Linköping University Electronic Press (LiU E-Press)
    • Abstract:
      The development of growth processes for the synthesis of high-quality epitaxial layers is one of the requirements for utilizing the ultrawide band gap semiconductor Ga2O3 for high-voltage, high-power electronics. A halide vapor phase epitaxy (HVPE) process used to grow beta-Ga2O3 layer was optimized by modifying the gas inlet, resulting in improved growth uniformity. A conventional tube acting as an inlet for the Ga precursor GaCl gas was replaced with a shower head with four outlets at 45 degrees to the horizontal axis of the reactor. The modification was performed based on numerical calculations of the three-dimensional distribution of gases inside the growth chamber with different designs of the GaCl precursor inlet. It was shown that variation in the Ga/O ratio over the substrate holder was similar to 10% for a shower head compared with similar to 40% for a tube. In addition, growth with a tube leads to the film thickness varying by a factor of similar to 4 depending on the position on the holder, whereas when using a shower head, the thickness of the grown Ga2O3 layers became much more uniform with a total spread of just similar to 30% over the entire substrate holder. ; Funding Agencies|Swedish Research Council; Swedish Energy Agency; [2018-04552]; [2019-05154]; [46563-1]
    • File Description:
      application/pdf
    • Relation:
      Crystals, 2073-4352, 2022, 12:12; orcid:0000-0002-9840-7364; orcid:0000-0002-2597-3322; http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-191051; ISI:000905604600001
    • Accession Number:
      10.3390/cryst12121790
    • Online Access:
      http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-191051
      https://doi.org/10.3390/cryst12121790
    • Rights:
      info:eu-repo/semantics/openAccess
    • Accession Number:
      edsbas.31C7055A