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Fe(OTf) 3 ‑Catalyzed Diastereoselective Synthesis of α‑Aminophosphonates via Phosphorylation of N,O -Acetals

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  • Additional Information
    • Publication Date:
      2025
    • Collection:
      The Open University: Figshare
    • Abstract:
      An efficient approach to α - aminophosphonates has been developed through an Fe(OTf) 3 -catalyzed N- α phosphonylation of N,O -acetals with triethyl phosphite. As a result, a series of 2,6- cis and 2,5- trans α - aminophosphonates were obtained in moderate to excellent yields and with excellent diastereoselectivities ( dr up to 19:1).
    • Accession Number:
      10.1021/acs.joc.5c01554.s001
    • Online Access:
      https://doi.org/10.1021/acs.joc.5c01554.s001
      https://figshare.com/articles/journal_contribution/Fe_OTf_sub_3_sub_Catalyzed_Diastereoselective_Synthesis_of_Aminophosphonates_via_Phosphorylation_of_i_N_O_i_-Acetals/29988662
    • Rights:
      CC BY-NC 4.0
    • Accession Number:
      edsbas.85095813