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Synthesis and characterization of a composite anion exchange membrane for water electrolyzers (AEMWE)

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  • Additional Information
    • Contributors:
      Rakhshani, Somayyeh; Araneo, Rodolfo; Pucci, Andrea; Rinaldi, Antonio; Giuliani, Chiara; Pozio, Alfonso
    • Publication Information:
      MDPI
    • Publication Date:
      2023
    • Collection:
      Sapienza Università di Roma: CINECA IRIS
    • Abstract:
      Anion exchange membranes (AEM) have gained attention recently as a promising candidate for low-cost water electrolysis systems to produce hydrogen, linked with renewable energy resources as a sustainable alternative to fossil fuels. The development of potential materials for producing and analyzing AEM is an imperative step towards commercialization and plays a competitive role in the hydrogen production industry. In this article, we developed a composite anion exchange membrane prepared by activating a commercial support structure (Celgard® 3401) with a commercially available functional group (Fumion® FAA-3) through a phase-inversion process. Fourier-transform infrared spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) analysis demonstrated the phase-inversion procedure as an effective methodology. Furthermore, the cell performance test result (with Celgard/Fumion) was very promising and even better in comparison with a commercial membrane commonly applied in alkaline electrolysis (Fumasep). We also developed a testing procedure for membrane performance evaluation during electrolysis which is very critical considering the effect of CO2 absorption on membrane conductivity.
    • Relation:
      info:eu-repo/semantics/altIdentifier/pmid/36676916; info:eu-repo/semantics/altIdentifier/wos/WOS:000918982200001; volume:13; issue:1; firstpage:1; lastpage:15; numberofpages:15; journal:MEMBRANES; https://hdl.handle.net/11573/1666886
    • Accession Number:
      10.3390/membranes13010109
    • Online Access:
      https://hdl.handle.net/11573/1666886
      https://doi.org/10.3390/membranes13010109
    • Rights:
      info:eu-repo/semantics/openAccess
    • Accession Number:
      edsbas.9157F4C4