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Phase Transitions in Finite Systems using Information Theory

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  • Additional Information
    • Contributors:
      Grand Accélérateur National d'Ions Lourds (GANIL); Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS); Laboratoire de physique corpusculaire de Caen (LPCC); Université de Caen Normandie (UNICAEN); Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN); Normandie Université (NU)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
    • Publication Information:
      HAL CCSD
    • Publication Date:
      2007
    • Collection:
      Normandie Université: HAL
    • Subject Terms:
    • Abstract:
      International audience ; (abridged) In this paper, we present the issues we consider as essential as far as the statistical mechanics of finite systems is concerned. In particular, we emphasis our present understanding of phase transitions in the framework of information theory. Information theory provides a thermodynamically-consistent treatment of finite, open, transient and expanding systems which are difficult problems in approaches using standard statistical ensembles. As an example, we analyze is the problem of boundary conditions, which in the framework of information theory must also be treated statistically. We recall that out of the thermodynamical limit the different ensembles are not equivalent and in particular they may lead to dramatically different equation of states, in the region of a first order phase transition. We recall the recent progresses achieved in the understanding of first-order phase transition in finite systems: the equivalence between the Yang-Lee theorem and the occurrence of bimodalities in the intensive ensemble and the presence of inverted curvatures of the thermodynamic potential of the associated extensive ensemble.
    • Relation:
      info:eu-repo/semantics/altIdentifier/arxiv/0712.1002; in2p3-00194045; https://hal.in2p3.fr/in2p3-00194045; https://hal.in2p3.fr/in2p3-00194045/document; https://hal.in2p3.fr/in2p3-00194045/file/chomaz-6s.pdf; ARXIV: 0712.1002
    • Accession Number:
      10.1063/1.2839119
    • Online Access:
      https://hal.in2p3.fr/in2p3-00194045
      https://hal.in2p3.fr/in2p3-00194045/document
      https://hal.in2p3.fr/in2p3-00194045/file/chomaz-6s.pdf
      https://doi.org/10.1063/1.2839119
    • Rights:
      info:eu-repo/semantics/OpenAccess
    • Accession Number:
      edsbas.B9358288