Consequences of repeated hyperbaric hydrogen exposures on mechanical properties and microstructure of polyamide 11

The objective was to evaluate the impact of repeated exposure to hyperbaric hydrogen (90 MPa; 30 °C) and pressure release on the microstructure and mechanical behavior of PA11. Samples were analyzed after 1, 2, 5 and 10 cycles, by SAXS, WAXS, DMA, DSC, and a series of mechanical tests with variable triaxiality ratio. The most visible change in the residual state after desorption was a stiffening of the amorphous phase. It mainly originated from the first cycle, especially the first pressurization. The crystalline phase was slightly affected and no evidence of nano-voiding was brought in the residual state up to 10 cycles. Similar analyses were conducted during the first cycle's desorption transient. They showed a reversible plasticizing effect and a trend of nano-voiding vanishing after desorption but might promote damage upon further triaxial loading.